地洼盆地砂岩铜矿床成矿作用的化学动力学和热力学研究     

谭凯旋 Kaixu.  T 《大地构造与成矿学》1996,20(3):229-237

对我国南方中新生代地洼盆地中的砂岩铜矿床进行了化学动力学与热力学的理论与实验研究。矿源岩中以辉铜矿和黄铜矿最有利于溶解和迁移，ＮａＣｌ对Ｃｕ的溶解和含矿流体的形成起了催化作用。溶液中Ｃｕ以络合物的形式迁移，其中以一价铜氯络合物为主；温度的降低和溶液中性化导致了络合物的失稳、分解和铜矿物的沉淀。铜矿物的化学动力学和热力学制约了砂岩铜矿中以辉铜矿为主及矿床分带的形成。  相似文献   

高温超高压下Ni40Mn30Fe30与叶蜡石反应的研究     

朱成明  金志升 《矿物学报》1996,16(4):370-376

本文对Ｎｉ４０Ｍｎ３０Ｆｅ３０合金与在不同焙烧温度下得到的含水叶蜡，在高温超高压下的反应进行了实验研究，温度测至１４２０℃，压是至５．５ＧＰａ，研究了该反应的物质－化学机制，以及反应速率与温度，压力，含水量等参数的关系，对高压下物质迁移运动的固有特征进行了探讨。  相似文献   

A New Interpretation of Centimetre-scale Variations in the Progress of Infiltration-driven Metamorphic Reactions: Case Study of Carbonated Metaperidotite, Val d'Efra, Central Alps, Switzerland   总被引：1，自引：0，他引：1  

FERRY  JOHN M.; RUMBLE  DOUGLAS  III; WING  BOSWELL A.; PENNISTON-DORLAND  SARAH C. 《Journal of Petrology》2005,46(8):1725-1746

Progress () of the infiltration-driven reaction, 4olivine +5CO₂ + H₂O = talc + 5magnesite, that occurred during Barrovianregional metamorphism, varies at the cm-scale by a factor of3·5 within an 3 m³ volume of rock. Mineral and stableisotope compositions record that X_CO2, ¹⁸O_fluid, and ¹³C_fluidwere uniform within error of measurement in the same rock volume.The conventional interpretation of small-scale variations in in terms of channelized fluid flow cannot explain the uniformityin fluid composition. Small-scale variations in resulted insteadbecause (a) reactant olivine was a solid solution, (b) initiallythere were small-scale variations in the amount and compositionof olivine, and (c) fluid composition was completely homogenizedover the same scale by diffusion–dispersion during infiltrationand subsequent reaction. Assuming isochemical reaction, spatialvariations in image variations in the (Mg + Fe)/Si of the parentrock rather than the geometry of metamorphic fluid flow. Ifinfiltration-driven reactions involve minerals fixed in composition,on the other hand, spatial variations in do directly imagefluid flow paths. The geometry of fluid flow can never be determinedfrom geochemical tracers over a distance smaller than the oneover which fluid composition is completely homogenized by diffusion–dispersion. KEY WORDS: Alpine Barrovian metamorphism; diffusion; metamorphic fluid composition; metamorphic fluid flow; reaction progress  相似文献   

Genetic relationship of metamorphic reaction and dehydration-melting     

Fulai Liu  Qihan Shen  Yuansheng Eng  Xuechun Xu  Rui Ma 《中国科学D辑(英文版)》1998,41(1):49-56

The high-temperature and pressure experimental data of garnet, sillimantite and biotite-bearing potash feldspar gneiss (SGBG, natural block rock) has shown that metamorphic reactions between garnet and melt, and mineral assemblage evolutional features are not only controlled byP-T condition, but also genetically correlate with dehydration-melting of biotite and partial melting of felsic minerals. Combining experimental data with theoretical analyses, the genetic mechanism of metamorphic reaction and its dynamic significance have been demonstrated in the process of metamorphic evolution of khondalite series on the border of Jin (Shanxi Province)-Inner Mongolia. Project supported by the Youth Geologist Foundation of Ministry of Geology and Mineral Resources of China, the Post-docter Foundation and the National Natural Science Foundation of China (Grant No. 49572138).  相似文献   

蔓箐沟一带石榴基性麻粒岩变质反应与矿物演化     

刘福来 《吉林大学学报(地球科学版)》1998,(1)

蔓箐沟地区石榴基性麻粒岩发育多期变质反应结构。矿物组合演化可划分三个阶段：①峰期阶段（Ｍ１）,以包裹于石榴石中的Ｏｐｘ＋Ｃｐｘ±Ｈｂ＋Ｐｌ±Ｑｚ和由Ｇｔ＋Ｏｐｘ＋Ｃｐｘ±Ｈｂ＋Ｐｌ±Ｑｚ组成基质矿物组合为代表;②退变早期近等温减压阶段（Ｍ２）,形成蠕虫状后成合晶Ｏｐｘ＋Ｈｂ＋Ｐｌ±Ｍｔ;③退变晚期阶段（Ｍ３）,则形成细粒、黄绿色Ｈｂ＋中酸性Ｐｌ的较低温组合。并揭示该区石榴基性麻粒岩从中下部地壳的麻粒岩相变质,到快速抬升至中浅部地壳发生的近等温减压及晚期降温退变的复杂ｐＴ演化历史。  相似文献   

Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes     

Eric Grosjean  Daniel Grosjean 《Journal of Atmospheric Chemistry》1996,24(2):141-156

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.  相似文献   

A continuous and mechanistic representation of calcite reaction-controlled kinetics in dilute solutions at 25°C and 1 atm total pressure     

Takeshi Arakaki  Alfonso Mucci 《Aquatic Geochemistry》1995,1(1):105-130

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THE INFLUENCE OF PHOTOCHEMICAL PROCESS ON THE ATMOSPHERIC WAVE^*          下载免费PDF全文

Xu Jiyao  Wang Yingjian 《Acta Meteorologica Sinica》1998,12(4):459-462

The time damping rate of gravity wave in the range of 30-70 km is calaclated in three circumstances:(1) adiabatic process,(2) diabatic process caused by atmospheric cooling,and(3) diabatic process resulting from atmospheric photochemical heating and cooling.The results indicate that the photochemical heating is as important as Newtonian cooling and its contribution to the time damping rate of gravity wave can not he negligible.  相似文献   

THE INFLUENCE OF PHOTOCHEMICAL PROCESS ON THE ATMOSPHERIC WAVE     

徐寄遥  王英鉴 《Acta Meteorologica Sinica》1998,(4)

The time damping rate of gravity wave in the range of 30-70 km is calaclated in threecircumstances:(1)adiabatic process,(2)diabatic process caused by atmospheric cooling,and(3)diabatic process resulting from atmospheric photochemical heating and cooling.The resultsindicate that the photochemical heating is as important as Newtonian cooling and its contribution tothe time damping rate of gravity wave can not he negligible.  相似文献   

Measurements of Reaction Coefficients of NO2 and HONO on Aerosol Particles     

Roy M. Harrison  Gareth M. Collins 《Journal of Atmospheric Chemistry》1998,30(3):397-406

The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO₂ afford a reaction coefficient in the range (2.8–10) × 10^-4 and for HONO, (2.8–4.6) × 10^-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO₂. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.  相似文献